Two novel manganese coordination polymers containing both double-stranded chain and single chain or double-stranded chain

被引：51

作者：

Zhou, JH

Zhu, X

Zhang, YN

Zhang, Y

Li, BL ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synthesis Jiangsu Prov, Suzhou 215006, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 08期

关键词：

manganese; crystal structure; bis(triazole) ligand; different topologies; conformation;

D O I：

10.1016/j.inoche.2004.06.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of bis(1,2,4-triazol-1-yl)ethane (bte), MnSo(4) (.) H2O with KNCS or NaN(CN)(2) yields two novel polymers [Mn(gauchebte)(2)(NCS)2](n .) [Mn(anti-bte)(H2O)(2)(NCS)(2)](n) (1) which contains both double-stranded chain and single chain and both the gauche and anti conformations bte, and forms three-dimensional hydrogen bond network, and {Mn(gauche-bte)(2)[N(CN)(2)](2)}(n) (2) which contains double-stranded chain. (C) 2004 Elsevier B.V. All rights reserved.

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收藏

页码：949 / 952

页数：4

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