Novel double-stranded chains vs two-layer interwoven sheets.: Subtle coligand effects and related properties for [CO(Py2S)2X2]n (Py2S = 4,4′-dipyridyl sulfide; X = NCS, Cl)

被引：113

作者：

Jung, OS ^{[1
]}

Park, SH ^{[1
]}

Kim, DC ^{[1
]}

Kim, KM ^{[1
]}

机构：

[1] Korea Inst Sci & Technol, Mat Chem Res Ctr, Seoul 136791, South Korea

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 04期

关键词：

D O I：

10.1021/ic971415x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel Double-Stranded Chains vs Two-Layer Interwoven Sheets. Subtle Coligand Effects and Related Properties for [Co(Py2S)(2)X-2](n) (Py2S = 4,4'-Dipyridyl Sulfide; X = NCS, CI). A study of striking structural differences in the magic angle of Py2S and coligand effects has been carried out. [Co(Py2S)(2)Cl-2](n) is the first integral two-layer interwoven sheet without any counterion or solvate whereas [Co(Py2S)(2)(NCS)(2)](n) affords a double-stranded linear infinite structure. Thermal analyses of the complexes over the temperature range 25-430 degrees C show the significant thermal behaviors associated with the structure.

引用

页码：610 / +

页数：3

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