Photo-induced tautomerisation of methyltrioxorhenium(VII): the intermediate in olefin metathesis?

被引：20

作者：

Morris, LJ

Downs, AJ

Greene, TM

McGrady, GS

Herrmann, WA

Sirsch, P

Gropen, O

Scherer, W

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Kings Coll London, Dept Chem, London WC2R 2LS, England

[3] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

[4] Univ Tromso, Inst Math & Phys Sci, N-9037 Tromso, Norway

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 01期

关键词：

D O I：

10.1039/a907908d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)(2)OH] under the influence of UV light; the carbene has been characterised in its normal and H-2- and C-13-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

引用

页码：67 / 68

页数：2

共 17 条

[11]

Hoffman D. M., 1995, COMPREHENSIVE ORGANO, V6, P231

[12] PHOTOCHEMISTRY OF METHYLTRIOXORHENIUM(VII) [J].