Rare earth activated nanosized oxide phosphors: synthesis and optical properties

被引:108
作者
Sun, LD [1 ]
Yao, J [1 ]
Liu, CG [1 ]
Liao, CS [1 ]
Yan, CH [1 ]
机构
[1] Peking Univ, Coll Chem, PKU HKU Joint Lab Mat Chem & Biochem, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
rare earth; nanocrystals; photoluminescence;
D O I
10.1016/S0022-2313(99)00471-8
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Gd2O3 : Eu and (Gd2Y)(2)O-3 : Eu nanocrystals were prepared by the glycine assist combustion method. The as-prepared products are porous networks from the HTEM and isolated nanoparticles can be observed after further annealing. From the luminescence spectra and XRD patterns, the prepared Gd2O3 :EU nanocrystals were found to be monoclinic. While Y3+ doped into the Gd2O3 to form the complex host, the structure changed from monoclinic to cubic when Y3+/Gd3+ is 0.3. More interesting, the luminescent intensity of the (Gd,Y)(2)O-3 : Eu nanocrystals is higher than that of pure Y2O3 : Eu or Gd2O3 : Eu system. Besides XRD pattern, the luminescence spectra, another powerful evidence in deducing the crystal structure, are used for analysis. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:447 / 450
页数:4
相关论文
共 10 条
[1]   OPTICAL-PROPERTIES OF MANGANESE-DOPED NANOCRYSTALS OF ZNS [J].
BHARGAVA, RN ;
GALLAGHER, D ;
HONG, X ;
NURMIKKO, A .
PHYSICAL REVIEW LETTERS, 1994, 72 (03) :416-419
[2]   Laser spectroscopy of nanocrystalline Eu2O3 and Eu3+:Y2O3 [J].
Eilers, H ;
Tissue, BM .
CHEMICAL PHYSICS LETTERS, 1996, 251 (1-2) :74-78
[3]   The Y2BaCuO5 oxide as green pigment in ceramics [J].
Fernandez, F ;
Colon, C ;
Duran, A ;
Barajas, R ;
d'Ors, A ;
Becerril, M ;
Llopis, J ;
Paje, SE ;
Saez-Puche, R ;
Julian, I .
JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 275 :750-753
[4]   Yttrium oxide:Eu3+ red phosphor by self-propagating high temperature: Synthesis [J].
Kottaisamy, M ;
Jeyakumar, D ;
Jagannathan, R ;
Rao, MM .
MATERIALS RESEARCH BULLETIN, 1996, 31 (08) :1013-1020
[5]   Growth and characterization of Y2O3:Eu3+ phosphor films by sol-gel process [J].
Rao, RP .
SOLID STATE COMMUNICATIONS, 1996, 99 (06) :439-443
[6]   Preparation and fluorescence spectroscopy of bulk monoclinic Eu3+:Y2O3 and comparison to Eu3+:Y2O3 nanocrystals [J].
Williams, DK ;
Bihari, B ;
Tissue, BM ;
McHale, JM .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (06) :916-920
[7]   Nanophased CoFe2O4 prepared by combustion method [J].
Yan, CH ;
Xu, ZG ;
Cheng, FX ;
Wang, ZM ;
Sun, LD ;
Liao, CS ;
Jia, JT .
SOLID STATE COMMUNICATIONS, 1999, 111 (05) :287-291
[8]   Combustion synthesis and photoluminescence of nanocrystalline Y2O3:Eu phosphors [J].
Ye, T ;
Zhao, GW ;
Zhang, WP ;
Xia, SD .
MATERIALS RESEARCH BULLETIN, 1997, 32 (05) :501-506
[9]   Luminescence of nanometric scale Y2SiO5:Eu-3 [J].
Yin, M ;
Zhang, W ;
Xia, S ;
Krupa, JC .
JOURNAL OF LUMINESCENCE, 1996, 68 (06) :335-339
[10]   LOW-DIMENSIONAL SYSTEMS - QUANTUM-SIZE EFFECTS AND ELECTRONIC-PROPERTIES OF SEMICONDUCTOR MICROCRYSTALLITES (ZERO-DIMENSIONAL SYSTEMS) AND SOME QUASI-2-DIMENSIONAL SYSTEMS [J].
YOFFE, AD .
ADVANCES IN PHYSICS, 1993, 42 (02) :173-266