Nanoporous metal-containing nickel phosphates:: A class of shape-selective catalyst

被引：46

作者：

Chang, JS

Hwang, JS

Jhung, SH

Park, SE

Férey, G

Cheetham, AK

机构：

[1] KRICT, Catalysis Ctr Mol Engn, Taejon 305600, South Korea

[2] Inha Univ, Dept Chem, Inchon 402751, South Korea

[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[4] Univ Versailles, Inst Lavoisier, UMR 8637, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 21期

关键词：

heterogeneous catalysis; microporous materials; nickel; phosphates; zeolite analogues;

D O I：

10.1002/anie.200353502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A substitute for zeolites: The nanoporous nickel phosphate VSB-1 exhibits zeolitic properties and very weak acidity and basicity (see picture). When VSB-1 is modified by metal-ion exchange or through metal incorporation into the framework, it offers promising catalytic properties, such as shape selectivity, and activity in both redox catalysis and photocatalysis.

引用

页码：2819 / 2822

页数：4

共 36 条

[1] Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(II) phosphate, VSB-1 [J].