Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?

被引：439

作者：

Cavani, Fabrizio ^{[1
]}

Teles, Joaquim Henrique ^{[2
]}

机构：

[1] ALMA MATER STUDIORUM Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy

[2] BASF SE, Basic Chem Res, D-67056 Ludwigshafen, Germany

来源：

CHEMSUSCHEM | 2009年 / 2卷 / 06期

关键词：

alkanes; catalysis; chemical engineering; oxidation; sustainable chemistry; LIQUID-PHASE OXIDATION; N-BUTANE OXIDATION; ISOBUTANE SELECTIVE OXIDATION; GOLD-TITANIA CATALYSTS; V-O CATALYSTS; VANADIUM PHOSPHATE CATALYSTS; CHEMICAL-PHYSICAL FEATURES; METAL-OXIDE CATALYSTS; SHORT-CHAIN ALKANES; PROPANE AMMOXIDATION;

D O I：

10.1002/cssc.200900020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Review documents some examples of recent innovations in the field of catalytic selective oxidation from an industrial point of view. The use of alkanes as building blocks for the synthesis of bulk chemicals and intermediates is discussed, along with the main properties that catalysts should possess inorder to efficiently catalyse the selective oxidation of these hydrocarbons. The currently developed processes for propene oxide and new processes under investigation for the synthesis of adipic acid are also described, highlighting innovative aspects for a better sustainability of the chemical industry. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：508 / 534

页数：27

共 467 条

[21] The role of catalysis in the design, development, and implementation of green chemistry [J].