A pentagonal pyramidal zirconium imido complex for catalytic hydroamination of unactivated alkenes

被引：142

作者：

Thomson, Robert K. ^{[1
]}

Bexrud, Jason A. ^{[1
]}

Schafer, Laurel L. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 17期

关键词：

D O I：

10.1021/om060545n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry.

引用

页码：4069 / 4071

页数：3

共 43 条

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