Hydrothermal synthesis, crystal structure and photoluminescent properties of a novel 3-D coordination polymer [Cd2(pydc)2(H2O)]n (pydc = pyridine-2,3-dicarboxylate)

被引：66

作者：

Han, Zheng-Bo ^{[1
]}

Ma, Yi

Sun, Zhen-Gang

You, Wan-Sheng

机构：

[1] Liaoning Univ, Sch Chem Sci & Engn, Shenyang 110036, Peoples R China

[2] Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116029, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 08期

关键词：

synthesis; crystal structure; coordination polymer; luminescent properties; COMPLEXES; FRAMEWORK; INTERPENETRATION; MOLECULES; LIGANDS; CD(II); SHEETS;

D O I：

10.1016/j.inoche.2006.05.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 3-D coordination polymer [Cd-2(pydc)(2)(H2P)](n) (pydc = pyridine-2,3-dicarboxylate) 1 has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and the single crystal X-ray diffraction. The title compound consists of two kinds of Cd(II) center with different coordination environments by pydc and aqua ligands, to form a 3-D open framework. Compound 1 display strong fluorescent emission in the solid state at room temperature. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：844 / 847

页数：4

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