Fabrication of self-assembled polyaniline films by doping-induced deposition

被引：37

作者：

Li, D ^{[1
]}

Jiang, YD

Wu, ZM

Chen, XD

Li, YR

机构：

[1] Nanjing Univ Sci & Technol, Dept Chem Engn, Mat Chem Lab, Nanjing 210094, Peoples R China

[2] Univ Elect Sci & Technol China, Dept Mat Sci & Engn, Chengdu 610054, Peoples R China

来源：

THIN SOLID FILMS | 2000年 / 360卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

polyaniline; poly(styrenesulfonic acid); self-assembly; conducting polymer;

D O I：

10.1016/S0040-6090(99)00948-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The ultrathin films of polyaniline (PAni)/poly (styrenesulfonic acid)(PSSA) were fabricated via a novel self-assembling process by alternately immersing the substrates into dilute PAni solution in N-methylpyrrolidinone (NMP) and the aqueous solution of PSSA. The process was characterized by W-Vis absorption spectroscopy. It was found that the oxidation state of polyaniline in single monolayers was dependent on the thickness of the film. The self-assembling mechanism was based on the acid-base reaction between PAni and PSSA. The thickness of the films can be easily manipulated at nanometer scale by controlling the solution chemistry and recycling times. The resulting films are uniform and adhere strongly to the substrates. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：24 / 27

页数：4

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