Hydrogen-induced 3 x 1 phase of the Si-rich 3C-SiC(001) surface

被引:18
作者
Yeom, HW [1 ]
Matsuda, I
Chao, YC
Hara, S
Yoshida, S
Uhrberg, RIG
机构
[1] Univ Tokyo, Dept Appl Chem, Tokyo 1130033, Japan
[2] Univ Tokyo, Dept Chem, Tokyo 1130033, Japan
[3] Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden
[4] Electrotech Lab, Tsukuba, Ibaraki 305, Japan
来源
PHYSICAL REVIEW B | 2000年 / 61卷 / 04期
关键词
D O I
10.1103/PhysRevB.61.R2417
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A single-domain 3 x 1 phase induced by hydrogen adsorption on a Si-rich 3C-SiC(001)3 x 2 surface is investigated by photoemission using synchrotron radiation. Three surface components of the Si 2p core level are identified for the 3 x 1-H phase, which resemble those of the 3 x 2 surface. A H-Si bonding state is observed by angle-resolved valence-band photoemission. These results are consistent with the recent assignments of the Si 2p surface components and the valence band spectra of the 3 x 2 surface, based on the 3 x 2 structure model with 2/3 ML Si addimers. A straightforward 3 x 1-H structure model is introduced featuring Si dimer-bond breaking and dangling-bond saturation.
引用
收藏
页码:R2417 / R2420
页数:4
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