Synthesis and electrical conductivities of some metal complexes with the extended dithiolato ligand having a C8S8 skeleton

被引：32

作者：

Nakano, M

Kuroda, A

Maikawa, T

Matsubayashi, GE

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Toyonaka, Osaka 560, 1-16, Machikaneyama

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 284卷

关键词：

D O I：

10.1080/10587259608037932

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The new dithiolato ligand with an extended pi-electron system, C8H4S82-(2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene]-1,3-dithiole-4,5-dithiolate) was synthesized and [NBu(4)(n)][Au(C8H4S8)(2)] and Pt(C8H4S8)-(SEt(2))(2) prepared. Redox potentials of these complexes were determined. Their oxidized species and Na-1.5[Ni(C8H4S8)(2)] exhibit electrical conductivities of 0.06 - 17 S cm(-1) at room temperature for compacted pellets.

引用

页码：301 / 305

页数：5

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