Intramolecular aromatic hydroxylation mediated by a dinuclear iron complex:: an oxo-FeIV FeIV active intermediate is suggested

被引：29

作者：

Avenier, F ^{[1
]}

Dubois, L ^{[1
]}

Latour, JM ^{[1
]}

机构：

[1] CEA Grenoble, DRDC PMB, CNRS,UJF UMR 5155, Lab Physicochim Metaux Biol, F-38054 Grenoble 9, France

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 07期

关键词：

D O I：

10.1039/b402403f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of oxygen atom donors [XO, e. g., m-chloroperbenzoic acid (m-CPBA), o-tert-butylsulfone iodosyl benzene (ArIO)] the benzyl group of the ligand in a mixed-valent (FeFeIII)-Fe-II complex is almost quantitatively ortho-hydroxylated to a phenolate terminally bound to one iron in the derived (FeFeIII)-Fe-III complex. All available experimental evidence concurs to suggest that this reaction involves an oxo-(FeFeIV)-Fe-IV intermediate.

引用

页码：782 / 784

页数：3

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