Metastable sorption state of a metal-organic porous material determined by in situ synchrotron powder diffraction

被引：94

作者：

Kubota, Yoshiki ^{[1
]}

Takata, Masaki

Matsuda, Ryotaro

Kitaura, Ryo

Kitagawa, Susumu

Kobayashi, Tatsuo C.

机构：

[1] Osaka Prefecture Univ, Grad Sch Sci, Dept Phys Sci, Sakai, Osaka 5900035, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

[3] Okayama Univ, Dept Phys, Okayama 7008530, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 30期

关键词：

adsorption; metal-organic frameworks; microporous materials; structure elucidation; X-ray diffraction;

D O I：

10.1002/anie.200600976

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Guest-responsive framework: Gas adsorption into a metal-organic porous material was studies in situ. Structure analysis of empty phase I, intermediate phase M as a metastable state of gas adsorption, and saturated phase S showed rearrangement of guest molecules and framework transformation in response to guest size, shape, and amount. The picture shows these changes for the superimposed phases M and S. © 2006 Wiley-VCH Verlag GmbH © Co. KGaA.

引用

页码：4932 / 4936

页数：5

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