ortho-Hydroxylation of 4-tert-butylphenol by nonheme iron(III) complexes as a functional model reaction for tyrosine hydroxylase

被引：9

作者：

Funabiki, T

Yokomizo, T

Suzuki, S

Yoshida, S

机构：

[1] Department of Molecular Engineering, Graduated School of Engineering, Kyoto University

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a606878b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroxylation of 4-tert-butylphenol to 4-tert-butylcatechol is performed by a catecholatoiron(III) complex-hydroquinone-O-2 system which mimicks the roles of Fe2+ and Fe3+ in tyrosine hydroxylase; the ortho-hydroxylation of phenols by iron-oxygen active species is suggested.

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收藏

页码：151 / 152

页数：2

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