15-membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes.: A review

被引：36

作者：

Moreno-Mañas, M

Pleixats, R

Roglans, A

Sebastián, RM

Vallribera, A

机构：

[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

[2] Univ Girona, Dept Chem, Girona, Spain

来源：

ARKIVOC | 2004年

关键词：

alkene ligands; macrocycles; heterocycles; olefin complexes; catalysis;

D O I：

10.3998/ark.5550190.0005.414

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(E,E,E)- 1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.

引用

收藏

页码：109 / 129

页数：21

相关论文

共 36 条

[1] OBSERVATION OF CATALYTIC INTERMEDIATES IN THE SUZUKI REACTION BY ELECTROSPRAY MASS-SPECTROMETRY [J].

ALIPRANTIS, AO ;

CANARY, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) :6985-6986

[2] Electrospray ionization mass spectrometry detection of intermediates in the palladium-catalyzed oxidative self-coupling of areneboronic acids [J].

Aramendía, MA ;

Lafont, F ;

Moreno-Mañas, M ;

Pleixats, R ;

Roglans, A .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (10) :3592-3594

[3] The heck reaction as a sharpening stone of palladium catalysis [J].

Beletskaya, IP ;

Cheprakov, AV .

CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066

[4] Catalyst product separation techniques in Heck reaction [J].

Bhanage, BM ;

Arai, M .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2001, 43 (03) :315-344

[5] Preparation of nitrogen-containing 20-membered tetraolefinic macrocycles:: (E,E,E,E)-1,6,11,16-tetra(arylsulfonyl)-1,6,11,16-tetraaza-cycloicosa-3,8,13,18-tetraenes [J].

Blanco, B ;

Cerezo, S ;

Moreno-Mañas, M ;

Pleixats, R ;

Spengler, J .

TETRAHEDRON LETTERS, 2001, 42 (51) :9001-9003

[6] Characterization of reactive intermediates in palladium-catalyzed arylation of methyl acrylate (Heck reaction) [J].

Brown, JM ;

Hii, KK .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (06) :657-659

[7] The [(E,E,E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,18,13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids.: An approach to quinolines [J].

Cacchi, S ;

Fabrizi, G ;

Goggiamani, A ;

Moreno-Mañas, M ;

Vallribera, A .

TETRAHEDRON LETTERS, 2002, 43 (32) :5537-5540

[8]

Cerezo S, 1999, RAPID COMMUN MASS SP, V13, P2359, DOI 10.1002/(SICI)1097-0231(19991215)13:23<2359::AID-RCM799>3.0.CO

[9]

2-9

[10]

Cerezo S, 2001, EUR J INORG CHEM, P1999

← 1 2 3 4 →