15-membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes.: A review

被引：36

作者：

Moreno-Mañas, M

Pleixats, R

Roglans, A

Sebastián, RM

Vallribera, A

机构：

[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

[2] Univ Girona, Dept Chem, Girona, Spain

来源：

ARKIVOC | 2004年

关键词：

alkene ligands; macrocycles; heterocycles; olefin complexes; catalysis;

D O I：

10.3998/ark.5550190.0005.414

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(E,E,E)- 1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.

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页码：109 / 129

页数：21

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