Synthesis and crystal structure of one-dimensional copper(II) coordination polymer bridged by pyrazine derivative

被引：4

作者：

Adachi, K

Sugiyama, Y

Kumagai, H

Inoue, K

Kitagawa, S

Kawata, S

机构：

[1] Shizuoka Univ, Dept Chem, Shizuoka 4228529, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[3] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 376卷

关键词：

coordination polymer; copper; pyrazine derivative;

D O I：

10.1080/10587250210797

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-dimensional copper(II) coordination polymers [Cu(tdpd)(pda)](n) (1) (H(2)tdpd = 1,4,5,6-tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile, pda = 1,2-phenylenediamine) has been synthesized and characterized. Compound I is a linear chain of copper(II) ions bridged by tdpd(2-) dianion with terminal pda ligand. Magnetic susceptibility measurement shows antiferromagnetic couplings between the copper(II) ions.

引用

页码：71 / 76

页数：6

共 7 条

[1] Crystal structures and magnetic properties of novel coordination polymers with rectangular lattice constructed from pyrazine derivative [J].