Dramatic efficiency improvement in phosphorescent organic light-emitting diodes with ultraviolet-ozone treated poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)

被引:32
作者
Benor, Amare [1 ]
Takizawa, Shin-ya [1 ]
Chen, Ping [1 ]
Perez-Bolivar, Cesar [1 ]
Anzenbacher, Pavel, Jr. [1 ]
机构
[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA
关键词
charge injection; excitons; organic light emitting diodes; organic semiconductors; phosphorescence; polymer films; semiconductor thin films; work function; CONDUCTIVITY ENHANCEMENT; EMISSION; DEVICES;
D O I
10.1063/1.3132059
中图分类号
O59 [应用物理学];
学科分类号
摘要
The treatment of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) films by ultraviolet (UV) light-ozone to improve device efficiency was investigated utilizing two simple phosphorescent organic light-emitting diodes (PHOLEDs) architectures. The maximum external quantum efficiency in the first device increased from 3.5% for the untreated anode to 10.5%, while in the second device comprising an exciton blocking layer increased from 15.8% to 18.5%. The time dependence of the UV-ozone treatment on the performance was studied. The dramatic improvement in the PHOLED performance is attributed to the change in the PEDOT:PSS work function and more balanced charge injection, suggesting promising easy-to-do method to improve PHOLED performance.
引用
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页数:3
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