Polyimide as anode electrode material for rechargeable sodium batteries

被引：102

作者：

Chen, Long

Li, Wangyu

Wang, Yonggang

Wang, Congxiao

Xia, Yongyao ^{[1
]}

机构：

[1] Fudan Univ, Inst New Energy, Dept Chem, Shanghai 200433, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 48期

基金：

中国国家自然科学基金;

关键词：

NA-ION BATTERIES; LOW-COST; CATHODE; INSERTION; STORAGE; LI; TEREPHTHALATE; CAPACITY;

D O I：

10.1039/c4ra03473b

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A polyimide synthesized from 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTCDA) and ethylene diamine (EDA) was evaluated as a new anode material for sodium ion batteries (SIB). The polyimide delivers a discharge specific capacity of 140 mA h g(-1) at an average potential of 2 V vs. Na+/Na with an initial coulombic efficiency of 97.6% and exhibits an excellent cycleability with a capacity retention of 90% over 500 cycles. A full SIB with polyimide anode and Na3V2(PO4)(3)/C cathode and Na4Fe(CN)(6)/C cathode was proposed.

引用

收藏

页码：25369 / 25373

页数：5

相关论文

共 24 条

[1]

Sodium insertion in carboxylate based materials and their application in 3.6 V full sodium cells [J].

Abouimrane, Ali ;

Weng, Wei ;

Eltayeb, Hussameldin ;

Cui, Yanjie ;

Niklas, Jens ;

Poluektov, Oleg ;

Amine, Khalil .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (11) :9632-9638

[2]

Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[3]

Armand M, 2009, NAT MATER, V8, P120, DOI [10.1038/nmat2372, 10.1038/NMAT2372]

[4]

Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life [J].

Cao, Yuliang ;

Xiao, Lifen ;

Wang, Wei ;

Choi, Daiwon ;

Nie, Zimin ;

Yu, Jianguo ;

Saraf, Laxmikant V. ;

Yang, Zhenguo ;

Liu, Jun .

ADVANCED MATERIALS, 2011, 23 (28) :3155-+

[5]

THE MULTISTEP REVERSIBLE REDUCTION OF 1,4,5,8-NAPHTHALENE TETRACARBOXYLIC ACID DIANHYDRIDE - AN ELECTROCHEMICAL STUDY [J].

DELUCA, C ;

GIOMINI, C ;

RAMPAZZO, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 280 (01) :145-157

[6]

A low cost, all-organic Na-ion Battery Based on Polymeric Cathode and Anode [J].

Deng, Wenwen ;

Liang, Xinmiao ;

Wu, Xianyong ;

Qian, Jiangfeng ;

Cao, Yuliang ;

Ai, Xinping ;

Feng, Jiwen ;

Yang, Hanxi .

SCIENTIFIC REPORTS, 2013, 3

[7]

A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries [J].

Ellis, B. L. ;

Makahnouk, W. R. M. ;

Makimura, Y. ;

Toghill, K. ;

Nazar, L. F. .

NATURE MATERIALS, 2007, 6 (10) :749-753

[8]

Ghosh M.K., 1996, Polyimides: Fundamentals and Applications

[9]

Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries [J].

Jian, Zelang ;

Zhao, Liang ;

Pan, Huilin ;

Hu, Yong-Sheng ;

Li, Hong ;

Chen, Wen ;

Chen, Liquan .

ELECTROCHEMISTRY COMMUNICATIONS, 2012, 14 (01) :86-89

[10]

Komaba S., 2009, ECS Transactions, V16, P43, DOI DOI 10.1149/1.3112727