Effective Stabilization of a High-Loading Sulfur Cathode and a Lithium-Metal Anode in Li-S Batteries Utilizing SWCNT-Modulated Separators

被引:197
作者
Chang, Chi-Hao [1 ,2 ]
Chung, Sheng-Heng [1 ,2 ]
Manthiram, Arumugam [1 ,2 ]
机构
[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
关键词
CYCLE PERFORMANCE; POLYSULFIDE; INTERLAYER; PROSPECTS; LAYER; IMPROVE; PAPER;
D O I
10.1002/smll.201502505
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A custom single-wall carbon nanotube (SWCNT)-modulated separator is employed to directly suppress the polysulfide migration and indirectly protect the lithium-metal anode from severe polysulfide contamination. The conductive sp2-carbon scaffold continuously reactivates and reutilizes the trapped active material, so the SWCNT-modulated separator provides a facile way to facilitate the implementation of pure sulfur cathodes with high sulfur contents and loadings. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:174 / 179
页数:6
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