''Living radical'' polymerization of styrene in the presence of a nitroxide compound

被引：29

作者：

Hammouch, SO

Catala, JM

机构：

[1] Institut Charles Sadron (CNRS-ULP), 67083 Strasbourg, Cedex

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 10期

关键词：

D O I：

10.1002/marc.1996.030171003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of parameters such as styrene dilution and active site concentration on the polymerization of styrene in the presence of a di-tert-butyl nitroxide adduct (A-T) was examined. It is confirmed that the rate of styrene polymerization is independent of A-T concentration, with no monomer dilution effect. An increase in radical concentration generated in the medium leads to faster propagation, but the molecular weight of the polymers formed is alway controlled by the A-T concentration.

引用

页码：683 / 691

页数：9

共 14 条

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