Efficient synthesis of a carbocyclic core moiety with the stereochemistry of the C-1027 chromophore

被引：31

作者：

Sato, I ^{[1
]}

Akahori, Y ^{[1
]}

Iida, K ^{[1
]}

Hirama, M ^{[1
]}

机构：

[1] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 29期

关键词：

D O I：

10.1016/0040-4039(96)01036-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective and concise route to the bicyclo[7.3.0]dodecadiyne core moiety (26) of the C-1027 chromophore (1) through highly efficient LiN(TMS)(2)/CeCl3-mediated cyclization of alkynyl aldehyde 24 has been established. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5135 / 5138

页数：4