DMSO/N2H4•H2O/I2/H2O/CH3CN:: A new system for selective oxidation of alcohols in hydrated media

被引：50

作者：

Gogoi, P ^{[1
]}

Sarmah, GK ^{[1
]}

Konwar, D ^{[1
]}

机构：

[1] Reg Res Lab, Div Organ Chem, Jorhat 785006, Assam, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 15期

关键词：

D O I：

10.1021/jo0494984

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new alternative system for the oxidation of secondary alcohols to ketones with DMSO/N2H4-H2O/I-2/H2O/CH3CN in hydrated media has been developed. The system also selectively oxidizes the secondary alcoholic groups to the corresponding ketones in the presence of primary alcoholic groups present within the same molecule in moderate to very good yields at reflux temperature.

引用

页码：5153 / 5154

页数：2

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