Effect of structural and thermodynamic factors on the sorption of hydrogen by metal-organic framework compounds

被引：24

作者：

Kolotilov, S. V. ^{[1
]}

Pavlishchuk, V. V. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-03028 Kiev, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2009年 / 45卷 / 02期

关键词：

metal-organic frameworks; porous coordination polymers; hydrogen sorption; SECONDARY BUILDING UNITS; HIGH H-2 ADSORPTION; HIGH-SURFACE-AREA; COORDINATION POLYMER; CRYSTAL-STRUCTURE; PORE-SIZE; STORAGE; DESIGN; SITES; MOFS;

D O I：

10.1007/s11237-009-9068-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The characteristics of the sorption of hydrogen by metal-organic framework compounds (MOF) were examined, and the structural and thermodynamic factors that favor the sorption of H-2 by such substances were determined. The effect of the structure of the MOF and the size and geometry of the pores on the sorption characteristics was analyzed.

引用

页码：75 / 97

页数：23

共 104 条

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