Effect of structural and thermodynamic factors on the sorption of hydrogen by metal-organic framework compounds

被引：24

作者：

Kolotilov, S. V. ^{[1
]}

Pavlishchuk, V. V. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-03028 Kiev, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2009年 / 45卷 / 02期

关键词：

metal-organic frameworks; porous coordination polymers; hydrogen sorption; SECONDARY BUILDING UNITS; HIGH H-2 ADSORPTION; HIGH-SURFACE-AREA; COORDINATION POLYMER; CRYSTAL-STRUCTURE; PORE-SIZE; STORAGE; DESIGN; SITES; MOFS;

D O I：

10.1007/s11237-009-9068-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The characteristics of the sorption of hydrogen by metal-organic framework compounds (MOF) were examined, and the structural and thermodynamic factors that favor the sorption of H-2 by such substances were determined. The effect of the structure of the MOF and the size and geometry of the pores on the sorption characteristics was analyzed.

引用

页码：75 / 97

页数：23

共 104 条

[11] Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2:: The relative importance of accessible coordination sites and van der Waals interactions
Chapman, Karena W.
Chupas, Peter J.
Maxey, Evan R.
Richardson, James W.
[J]. CHEMICAL COMMUNICATIONS, 2006, (38) : 4013 - 4015
[12] Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues
Chapman, KW
Southon, PD
Weeks, CL
Kepert, CJ
[J]. CHEMICAL COMMUNICATIONS, 2005, (26) : 3322 - 3324
[13] Hydrogen adsorption in an interpenetrated dynamic metal-organic framework
Chen, Banglin
Ma, Shengqian
Zapata, Fatima
Lobkovsky, Emil B.
Yang, Jun
[J]. INORGANIC CHEMISTRY, 2006, 45 (15) : 5718 - 5720
[14] High H2 adsorption in a microporous metal-organic framework with open metal sites
Chen, BL
Ockwig, NW
Millward, AR
Contreras, DS
Yaghi, OM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) : 4745 - 4749
[15] Hydrogen storage in carbon nanotubes
Cheng, HM
Yang, QH
Liu, C
[J]. CARBON, 2001, 39 (10) : 1447 - 1454
[16] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
Chui, SSY
Lo, SMF
Charmant, JPH
Orpen, AG
Williams, ID
[J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
[17] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials
Chun, H
Dybtsev, DN
Kim, H
Kim, K
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) : 3521 - 3529
[18] Efficient hydrogen sorption in 8-connected MOFs based on trinuclear pinwheel motifs
Chun, Hyungphil
Jung, Heejin
Koo, Gumae
Jeong, Heondo
Kim, Dong-Kook
[J]. INORGANIC CHEMISTRY, 2008, 47 (12) : 5355 - 5359
[19] Hydrogen storage in metal-organic frameworks
Collins, David J.
Zhou, Hong-Cai
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3154 - 3160
[20] Hydrogen storage properties of metal nitroprussides M[Fe(CN)5NO], (M = Co, Ni)
Culp, JT
Matranga, C
Smith, M
Bittner, EW
Bockrath, B
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (16) : 8325 - 8328

← 1 2 3 4 5 6 7 8 9 10 →