Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues

被引：154

作者：

Chapman, KW ^{[1
]}

Southon, PD ^{[1
]}

Weeks, CL ^{[1
]}

Kepert, CJ ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 26期

关键词：

D O I：

10.1039/b502850g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The family of dehydrated nanoporous Prussian Blue analogues, M(II)3[Co-III(CN)(6)](2) (M-II = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.

引用

页码：3322 / 3324

页数：3

共 24 条

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