Conversion of Carbon Dioxide into Methanol with Silanes over N-Heterocyclic Carbene Catalysts

被引：515

作者：

Riduan, Siti Nurhanna ^{[1
]}

Zhang, Yugen ^{[1
]}

Ying, Jackie Y. ^{[1
]}

机构：

[1] Inst Bioengn & Nanotechnol, Singapore 138669, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 18期

关键词：

carbon dioxide; homogeneous catalysis; hydrosilylation; N-heterocyclic carbenes; IONIC LIQUIDS; COMPLEXES; HYDROSILYLATION; REDUCTION; 1,3-DIMETHYLIMIDAZOLIUM-2-CARBOXYLATE; CYANOSILYLATION; CARBOXYLATION; CHEMISTRY; ALDEHYDES; VERSATILE;

D O I：

10.1002/anie.200806058

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Activate and reduce: Carbon dioxide was reduced with silane using a stable N-heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition-metal catalysts for this reaction. This approach offers a very promising protocol for chemical CO 2 activation and fixation. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3322 / 3325

页数：4

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