A new trinuclear Cu(II) complex of inositol as a hydrogelator

被引：34

作者：

Joshi, Sachin A. ^{[1
]}

Kulkarni, Neelima D. ^{[1
]}

机构：

[1] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Vadodara 390002, Gujarat, India

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 17期

关键词：

SELF-ASSEMBLING ORGANOGELS; CRYSTAL-STRUCTURE; LUMINESCENT METALLOGELS; ION BINDING; METAL; MYOINOSITOL; GELATION; RELEASE; PROTEIN; COORDINATION;

D O I：

10.1039/b821283j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trinuclear copper(II) complex with inositol and 2,2'-bipyridine forms a. brous hydrogel at pH 12.4, the assembly of discrete trinuclear complex molecules to form the metallogel being assisted by H-bonding and inter- and intramolecular pi-stacking between the bipyridyls.

引用

页码：2341 / 2343

页数：3

共 55 条

[51] Evidence for C-H cleavage by an iron-superoxide complex in the glycol cleavage reaction catalyzed by myo-inositol oxygenase [J].

Xing, G ;

Diao, YH ;

Hoffart, LM ;

Barr, EW ;

Prabhu, KS ;

Arner, RJ ;

Reddy, CC ;

Krebs, C ;

Bollinger, JM .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (16) :6130-6135

[52] Oxygen activation by a mixed-valent, diiron(II/III) cluster in the glycol cleavage reaction catalyzed by myo-inositol oxygenase [J].

Xing, G ;

Barr, EW ;

Diao, YH ;

Hoffart, LM ;

Prabhu, KS ;

Arner, RJ ;

Reddy, CC ;

Krebs, C ;

Bollinger, JM .

BIOCHEMISTRY, 2006, 45 (17) :5402-5412

[53] Engineering target-responsive hydrogels based on aptamer - Target interactions [J].

Yang, Huanghao ;

Liu, Haipeng ;

Kang, Huaizhi ;

Tan, Weihong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6320-+

[54] Complexation of trivalent lanthanide cations by inositol in solid state.: The crystal structure and Raman spectra study of NdCl3•inositol•9H2O [J].

Yang, LM ;

Tao, DL ;

Sun, Y ;

Jin, XL ;

Zhao, Y ;

Yang, ZL ;

Weng, SF ;

Wu, JG ;

Xu, GX .

JOURNAL OF MOLECULAR STRUCTURE, 2001, 560 (1-3) :105-113

[55] A density functional theory investigation of metal ion binding sites in monosaccharides [J].

Zheng, YJ ;

Ornstein, RL ;

Leary, JA .

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1997, 389 (03) :233-240

← 1 2 3 4 5 6 →