Phosphine-olefin ligands:: a facile dehydrogenative route to catalytically active rhodium complexes

被引：43

作者：

Douglas, Thomas M. ^{[1
]}

Le Notre, Jerome ^{[1
]}

Brayshaw, Simon K. ^{[1
]}

Frost, Christopher G. ^{[1
]}

Weller, Andrew S. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 32期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b608129k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine - olefin complexes, some of which are catalytically active for 1,4-additions.

引用

页码：3408 / 3410

页数：3

共 26 条

[1] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[2] Versatile reactivity of the bis(dihydrogen) complex RuH2(H-2)(2)(PCy(3))(2) toward functionalized olefins: Olefin coordination versus hydrogen transfer via the stepwise dehydrogenation of the phosphine ligand [J].

Borowski, AF ;

SaboEtienne, S ;

Christ, ML ;

Donnadieu, B ;

Chaudret, B .

ORGANOMETALLICS, 1996, 15 (05) :1427-1434

[3] Alkane C-H activation and functionalization with homogeneous transition metal catalysts: a century of progress-a new millennium in prospect [J].

Crabtree, RH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (17) :2437-2450

[4] Potassium trifluoro(organo)borates: New perspectives in organic chemistry [J].

Darses, S ;

Genet, JP .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (22) :4313-4327

[5]

Deblon S, 2002, CHEM-EUR J, V8, P601, DOI 10.1002/1521-3765(20020201)8:3<601::AID-CHEM601>3.0.CO

[6]

2-C

[7] Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds [J].

Fagnou, K ;

Lautens, M .

CHEMICAL REVIEWS, 2003, 103 (01) :169-196

[8] Synthesis, neutron structure, and reactivity of the bis(dihydrogen) complex RuH2(η2-H2)2(PCyp3)2 stabilized by two tricyclopentylphosphines [J].

Grellier, M ;

Vendier, L ;

Chaudret, B ;

Albinati, A ;

Rizzato, S ;

Mason, S ;

Sabo-Etienne, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (50) :17592-17593

[9] Asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated aldehydes catalyzed by a chiral diene-rhodium complex [J].

Hayashi, T ;

Tokunaga, N ;

Okamoto, K ;

Shintani, R .

CHEMISTRY LETTERS, 2005, 34 (11) :1480-1481

[10] Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions [J].

Hayashi, T ;

Yamasaki, K .

CHEMICAL REVIEWS, 2003, 103 (08) :2829-2844

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