Multiwall carbon nanotube modified vinylester and vinylester -: based hybrid resins

被引:67
作者
Gryshchuk, O.
Karger-Kocsis, J.
Thomann, R.
Konya, Z.
Kiricsi, I.
机构
[1] Univ Kaiserslautern, Inst Verbundwerkstoffe GmbH, D-67663 Kaiserslautern, Germany
[2] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany
[3] Univ Freiburg, Freiburger Mat Forsch Zentrum, D-79104 Freiburg, Germany
[4] Univ Szeged, Appl & Environm Chem Dept, H-6720 Szeged, Hungary
关键词
nano-structures; thermosetting resins; electrical properties; fracture toughness; thermomechanical;
D O I
10.1016/j.compositesa.2005.09.003
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
Purified, catalytic chemically vapor deposited multiwall carbon nanotubes (MW-CNT) were incorporated in vinylester (VE), vinylester-urethane (VEUH) and vinylester/epoxy (VE/EP) systems in up to 2 wt% amount. The MW-CNT dispersion was studied by transmission electron microscopy (TEM). The electrical conductivity, thermomechanical, fracture mechanical and failure properties of the related nanocomposites were investigated. It was found that the MW-CNT of very high aspect ratio and thus prone for nesting can be only partly disintegrated. The effect of MW-CNT on the electrical conductivity was much larger than on the fracture mechanical performance. As MW-CNT can be treated as a flexible reinforcement its reinforcing efficiency is likely better in tough than in brittle thermosets. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1252 / 1259
页数:8
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