Polymer-clay nanocomposites exhibiting abnormal necking phenomena accompanied by extremely large reversible elongations and excellent transparency

被引:157
作者
Haraguchi, Kazutoshi [1 ]
Ebato, Mariko [1 ]
Takehisa, Toru [1 ]
机构
[1] Kawamura Inst Chem Res, Sakura, Chiba 2850078, Japan
关键词
D O I
10.1002/adma.200600143
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Soft and transparent polymer-clay nanocomposites (see figure), consisting of hydrophobic poly(2-methoxyethyl-acrylate) and hydrophilic inorganic clay, with a unique clay-network morphology have been synthesized by in situ free-radical polymerization. The nanocomposites exhibit the first observation of abnormal necking behavior accompanied by extremely large reversible elongation (1000-3000%) and excellent optical transparency, regardless of the clay content (1-30 wt %).
引用
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页码:2250 / +
页数:6
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