Phosphorolytic reactivity of o-iodosylcarboxylates and related nucleophiles

被引：186

作者：

Morales-Rojas, H ^{[1
]}

Moss, RA ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Biol Chem, New Brunswick, NJ 08903 USA

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 07期

关键词：

D O I：

10.1021/cr9405462

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iodosyl- and iodylcarboxylate derivatives are effective reagents for the hydrolytic cleavage of fluorophosphonate nerve agents as well as certain insecticides and phosphate triester simulants. Many iodosyl- and iodylcarboxylate derivatives and various delivery systems have been prepared and tested against a variety of phosphate triesters and phosphonate diesters. True turnover capability under mild conditions is the most important feature of IBA-related systems in comparison with other nucleophiles that only react stoichiometrically.

引用

页码：2497 / 2521

页数：25

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