Thiol-capping of CdTe nanocrystals:: An alternative to organometallic synthetic routes

被引:1468
作者
Gaponik, N [1 ]
Talapin, DV [1 ]
Rogach, AL [1 ]
Hoppe, K [1 ]
Shevchenko, EV [1 ]
Kornowski, A [1 ]
Eychmüller, A [1 ]
Weller, H [1 ]
机构
[1] Univ Hamburg, Inst Phys Chem, D-20146 Hamburg, Germany
关键词
D O I
10.1021/jp025541k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New approaches to synthesize photostable thiol-capped CdTe nanocrystals are reported. Post-preparative size-selective precipitation and selective photochemical etching have been developed as methods providing an increase of photoluminescence quantum efficiency of the nanocrystals of up to 40%. Some advantages of thiol-capping in comparison to conventional organometallic syntheses of quantum dots are discussed.
引用
收藏
页码:7177 / 7185
页数:9
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