Epoxidation of styrene with TBHP/O2 over ferrierite (FER) type molecular sieves

被引：13

作者：

Anand, R ^{[1
]}

Shevade, SS ^{[1
]}

Ahedi, RK ^{[1
]}

Mirajkar, SP ^{[1
]}

Rao, BS ^{[1
]}

机构：

[1] Natl Chem Lab, Catalysis Div, Poona 411008, Maharashtra, India

来源：

CATALYSIS LETTERS | 1999年 / 62卷 / 2-4期

关键词：

V-FER; Ti-FER; epoxidation; styrene oxide; TBHP;

D O I：

10.1023/A:1019099006237

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Epoxidation of styrene over vanadium silicalite with ferrierite (FER) type topology is undertaken. Influence of temperature, pressure, various solvents and solvent to substrate mole ratio was investigated. Conversion increased with increase in temperature and pressure. Solvent to substrate mole ratio is found to play a crucial role in increasing the conversion and selectivity. Catalytic activity of V-FER was compared with those of Ti-FER, TS-1 and Fe-FER. In the case of V- and Ti-ferrierite analogs, styrene oxide was the major product, whereas phenylacetaldehyde was the major product in the case of TS-1. The catalyst could be recycled after washing by a suitable solvent such as acetone and showed no significant loss in catalytic activity.

引用

页码：209 / 213

页数：5

共 16 条

[1] Synthesis Of FER titanosilicates from a non-aqueous alkali-free seeded system [J].

Ahedi, RK ;

Kotasthane, AN .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) :1685-1686

[2]

HATA E, 1993, Patent No. 025149

[3]

HOELDERICH WF, 1991, STUD SURF SCI CATAL, V58, P631

[4] OXIDATION OF STYRENE CATALYZED BY MU-OXOTRINUCLEAR MIXED-VALENCE AND MIXED METAL CARBOXYLATE COMPLEXES [J].

KANAI, H ;

HAYASHI, H ;

KOIKE, T ;

OHSUGA, M ;

MATSUMOTO, M .

JOURNAL OF CATALYSIS, 1992, 138 (02) :611-616

[5] EPOXIDATION OF STYRENE OVER A TITANIUM SILICATE MOLECULAR-SIEVE TS-1 USING DILUTE H2O2 AS OXIDIZING-AGENT [J].

KUMAR, SB ;

MIRAJKAR, SP ;

PAIS, GCG ;

KUMAR, P ;

KUMAR, R .

JOURNAL OF CATALYSIS, 1995, 156 (01) :163-166

[6]

MOOIWEER HH, 1994, STUD SURF SCI CATAL, V84, P2327

[7]

NERI C, 1984, Patent No. 0102097

[8] SKELETAL ISOMERIZATION OF 1-BUTENE ON 10-MEMBER RING ZEOLITE CATALYSTS [J].

OYOUNG, CL ;

PELLET, RJ ;

CASEY, DG ;

UGOLINI, JR ;

SAWICKI, RA .

JOURNAL OF CATALYSIS, 1995, 151 (02) :467-469

[9]

PARK YC, 1992, B KOR CHEM SOC, V13, P458

[10] CLEAVAGE OF THE CARBON CARBON DOUBLE-BOND OVER ZEOLITES USING HYDROGEN-PEROXIDE [J].

REDDY, JS ;

KHIRE, UR ;

RATNASAMY, P ;

MITRA, RB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1234-1235

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