Self assembly of silver(I) coordination polymers formed through hydrogen bonding with a new ditopic heteroscorpionate ligand

被引：26

作者：

Santillan, Guillermo A. ^{[1
]}

Carrano, Carl J. ^{[1
]}

机构：

[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA

来源：

DALTON TRANSACTIONS | 2009年 / 33期

关键词：

PI-PI STACKING; BIS(PYRAZOLYL)METHANE LIGANDS; SUPRAMOLECULAR ISOMERISM; METHANE LIGAND; COMPLEXES; NETWORKS; DESIGN; ANION; ARCHITECTURES; CONSTRUCTION;

D O I：

10.1039/b906047b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ditopic heteroscorpionate ligand, (3-methoxy-4-hydroxyphenyl)bis(3,5-dimethyl-pyrazolyl)methane (L5v), and four coordination polymers of silver Ag(I) derived therefrom, have been synthesized and characterized by X-ray diffraction, ESI-MS, IR spectroscopy and elemental analysis. The presence of different anions (i.e. BF4-, CF3SO3-, NO3-, or SbF6-) lead to different crystal packing schemes due to different H-bonding patterns that depend on the relative charge delocalization and/or shape of the anion.

引用

页码：6599 / 6605

页数：7

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