Detection and quantification of multiple molecular species in mainstream cigarette smoke by continuous-wave terahertz spectroscopy

被引:111
作者
Bigourd, Damien [1 ]
Cuisset, Arnaud [1 ]
Hindle, Francis [1 ]
Matton, Sophie [1 ]
Fertein, Eric [1 ]
Bocquet, Robin [1 ]
Mouret, Gael [1 ]
机构
[1] Univ Littoral Cote Opale, CNRS, UMR 8101, Lab Physicochim Atmosphere, F-59140 Dunkerque, France
关键词
D O I
10.1364/OL.31.002356
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Continuous-wave terahertz spectroscopy by photomixing is applied to the analysis of mainstream cigarette smoke. Using the wide tunability of the source, spectral signatures of hydrogen cyanide (HCN), carbon monoxide (CO), formaldehyde (H2CO), and water (H2O) have been observed from 500 to 2400 GHz. The fine spectral purity allows direct concentration measurement from the pure rotational transitions of HCN and CO. The quantification of the measurement was validated by the means of a calibration gas containing CO. The potential of this technique for trace gas detection is demonstrated with an estimated detection limit of HCN equal to 9 parts in 10(6). (c) 2006 Optical Society of America.
引用
收藏
页码:2356 / 2358
页数:3
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