A novel coordination polymer containing both interdigitated 1D chains and interpenetrated 2D grids

被引：67

作者：

Ayyappan, P ^{[1
]}

Evans, OR ^{[1
]}

Lin, WB ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 13期

关键词：

D O I：

10.1021/ic025524+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A hydro(solvo)thermal reaction between zinc perchlorate and ethyl ester of a new pyridinecarboxylate bridging ligand of similar to17.6 Angstrom in length yields a unique coordination polymer which contains both interdigitated infinite 1D chains and interpenetrated 2D rhombohedral grids [Zn-2.5(L)(4)(mu(3)-OH)].(H2O)(5), 1, where L is 3-{[4-(4-pyridylethenyl)phenyl]ethenyl}benzoate. The 1D chains contain mu(3)-bridged hydroxy groups and have a [Zn-4(mu(3)-OH)(2)(L)(6)] stoichiometry, while the 2D grids have a Zn(L)(2) formula and diagonal distances of 31.7 and 25.2 Angstrom. Crystal data for 1: monoclinic space group P2/c, a = 15.686(2) Angstrom, b = 12.6103(16) Angstrom, c = 38.999(5) Angstrom, beta = 98.397(2)1, and Z = 4.

引用

页码：3328 / 3330

页数：3

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