Applications of surface X-ray scattering to electrochemistry problems

被引:128
作者
Nagy, Z [1 ]
You, H [1 ]
机构
[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
关键词
X-ray scattering; platinum oxidation; copper passivation; ruthenium dioxide electrode; single crystal electrode;
D O I
10.1016/S0013-4686(02)00223-2
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Applications of the synchrotron X-ray scattering technique to electrochemistry problems are briefly reviewed ranging from submonolayer level phenomena, through nanometer size phenomena, to submicron size phenomena; that is, covering the full range of the 'interphase' at an electrode surface. The examples include, (i) incipient oxidation/reduction of platinum single crystal surfaces; (ii) submonolayer/monolayer level oxidation/reduction of ruthenium dioxide single crystal surfaces; (iii) copper passivation/ depassivation; and (iv) anodic formation of porous silicon and silicon dioxide layers. The design of several X-ray/electrochemical cells is also described. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3037 / 3055
页数:19
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