Surfactant-mediated generation of iso-oriented dense and mesoporous crystalline metal-oxide layers

被引:52
作者
Brezesinski, Torsten
Groenewolt, Matthijs
Pinna, Nicola
Amenitsch, Heinz
Antonietti, Markus
Smarsly, Bernd M. [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[2] Univ Halle Wittenberg, Inst Organ Chem, D-06120 Halle, Germany
[3] Univ Aveiro, Dept Quim, CICECO, P-3810139 Aveiro, Portugal
[4] Austrian Acad Sci, Inst Biophys & Xray Struct Res, A-8043 Graz, Austria
关键词
D O I
10.1002/adma.200600154
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ordered mesoporous and dense films of crystallographically oriented metal oxides (e.g. MoO3, see figure and also cover) are obtained by evaporation-induced self-assembly followed by heating. This surfactant-directed facile methodology works for oxides with anisotropic unit cells, based on the interaction with surfactants during nucleation (soft epitaxy).
引用
收藏
页码:1827 / +
页数:6
相关论文
共 29 条
  • [1] Valence-band excitations in V2O5
    Atzkern, S
    Borisenko, SV
    Knupfer, M
    Golden, MS
    Fink, J
    Yaresko, AN
    Antonov, VN
    Klemm, M
    Horn, S
    [J]. PHYSICAL REVIEW B, 2000, 61 (19): : 12792 - 12798
  • [2] Self-assembly and crystallization Behavior of mesoporous, crystalline HfO2 thin films:: A model system for the generation of mesostructured transition-metal oxides
    Brezesinski, T
    Smarsly, B
    Iimura, K
    Grosso, D
    Boissiére, C
    Amenitsch, H
    Antonietti, M
    Sanchez, C
    [J]. SMALL, 2005, 1 (8-9) : 889 - 898
  • [3] The generation of mesostructured crystalline CeO2, ZrO2 and CeO2-ZrO2 films using evaporation-induced self-assembly
    Brezesinski, T
    Antonietti, M
    Groenewolt, M
    Pinna, N
    Smarsly, B
    [J]. NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) : 237 - 242
  • [4] Brinker CJ, 1999, ADV MATER, V11, P579, DOI 10.1002/(SICI)1521-4095(199905)11:7<579::AID-ADMA579>3.3.CO
  • [5] 2-I
  • [6] Epitaxial growth and properties of thin film oxides
    Chambers, SA
    [J]. SURFACE SCIENCE REPORTS, 2000, 39 (5-6) : 105 - 180
  • [7] Evolution of nanocrystallinity in periodic mesoporous anatase thin films
    Choi, SY
    Mamak, M
    Speakman, S
    Chopra, N
    Ozin, GA
    [J]. SMALL, 2005, 1 (02) : 226 - 232
  • [8] SURFACTANTS IN EPITAXIAL-GROWTH
    COPEL, M
    REUTER, MC
    KAXIRAS, E
    TROMP, RM
    [J]. PHYSICAL REVIEW LETTERS, 1989, 63 (06) : 632 - 635
  • [9] COPPEL M, 1989, PHYS REV LETT, V63, P632
  • [10] Periodically ordered nanoscale islands and mesoporous films composed of nanocrystalline multimetallic oxides
    Grosso, D
    Boissière, C
    Smarsly, B
    Brezesinski, T
    Pinna, N
    Albouy, PA
    Amenitsch, H
    Antonietti, M
    Sanchez, C
    [J]. NATURE MATERIALS, 2004, 3 (11) : 787 - 792