Point by point comparison of two thermosensitive polymers exhibiting a similar LCST:: Is the age of poly(NIPAM) over?

被引：1112

作者：

Lutz, Jean-Francois ^{[1
]}

Akdemir, Oezguer ^{[1
]}

Hoth, Ann ^{[1
]}

机构：

[1] Fraunhofer Inst Appl Polymer Res, Res Grp Nanotechnol Life Sci, D-14476 Golm, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 40期

关键词：

D O I：

10.1021/ja065324n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present Communication compares the thermosensitivity in dilute aqueous solutions of well-defined copolymers composed of 95% of 2-(2-methoxyethoxy)ethyl methacrylate (MEO2MA) and 5% of oligo(ethylene glycol) methacrylate (OEGMA, Mn = 475 g·mol-1) and poly(N-isopropylacrylamide) (PNIPAM) samples having similar degrees of polymerization and chain-ends. The thermoresponsive behavior of P(MEO2MA-co-OEGMA) was found to be overall comparable, and in some cases, superior to PNIPAM. Hence, P(MEO2MA-co-OEGMA) copolymers can be considered as ideal structures, which combine both the properties of poly(ethylene glycol) and PNIPAM in a single macromolecule. Copyright © 2006 American Chemical Society.

引用

页码：13046 / 13047

页数：2

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