Elemental fluorine .6. Fluorination of cyclic 1,3-diketones and related compounds

被引：16

作者：

Chambers, RD

Hutchinson, J

Batsanov, AS

Lehmann, CW

Naumov, DY

机构：

[1] UNIV DURHAM,SCI LABS,BNRL FLUOROCHEM LTD,DURHAM DH1 3LE,ENGLAND

[2] UNIV DURHAM,SCI LABS,CHEM CRYSTALLOG UNIT,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 18期

关键词：

D O I：

10.1039/p19960002271

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct fluorination of cyclic 1,3-diones gives 2-mono- and 2,2-di-fluorinated products. The monofluorinated compounds crystallise in their enol forms and the difluorinated compounds form stable monohydrates whose crystal structures have been elucidated, Direct fluorination of phloroglucinol double dagger in formic acid yields 1,1,3,3,5,5-hexafluoro-2,2,4,4,6,6-hexahydroxtcyclohexane.

引用

页码：2271 / 2275

页数：5

共 10 条

[1] Elemental fluorine .5. Reactions of 1,3-dithiolanes and thioglycosides with fluorine-iodine mixtures [J].