The synthesis and selected properties of new compounds:: Mg3Fe4(VO4)6 and Zn3Fe4(VO4)6

被引:37
作者
Kurzawa, M [1 ]
Blonska-Tabero, A [1 ]
机构
[1] Tech Univ Szczecin, Inst Chem Environm Protect, PL-71065 Szczecin, Poland
关键词
inorganic compounds; chemical synthesis; infrared spectroscopy; X-ray diffraction;
D O I
10.1016/S0025-5408(02)00718-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
New compounds: Mg3Fe4(VO4)(6) and Zn3Fe4(VO4)(6) were obtained from a solid state reaction. The temperatures of melting Of Mg3Fe4(VO4)(6) and Zn3Fe4(VO4)(6) amount to 950 +/- 5 and 850 +/- 5degreesC, respectively. The indexing results and the calculated unit cell parameters for both compounds are given and suggest that both phases are isotypic with Mn3Fe4(VO4)(6). The IR spectra of the above-mentioned compounds are presented. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:849 / 858
页数:10
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