Metal bis{(trifluoromethyl)sulfonyl}amide complexes: highly efficient Friedel-Crafts acylation catalysts

被引:103
作者
Earle, MJ
Hakala, U
McAuley, BJ
Nieuwenhuyzen, M
Ramani, A
Seddon, KR
机构
[1] Queens Univ Belfast, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland
[2] Univ Helsinki, Fac Sci, Dept Chem, Lab Organ Chem, FIN-00014 Helsinki, Finland
关键词
D O I
10.1039/b403650f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A range of metal bis{(trifluoromethyl)sulfonyl}amide complexes, including many unreported ones, have been synthesised, most of which have been found to be excellent Friedel-Crafts acylation catalysts in the absence of solvent; these reactions have also been carried out in ionic liquids, which allow the catalysts to be recycled and reused.
引用
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页码:1368 / 1369
页数:2
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