Adsorption isotherms of phenols from water onto macroreticular resins

被引:128
作者
Juang, RS [1 ]
Shiau, JY [1 ]
机构
[1] Yuan Ze Univ, Dept Chem Engn, Chungli 32026, Taiwan
关键词
phenol; 4-chlorophenol; macroreticular resins; adsorption; isotherm analysis;
D O I
10.1016/S0304-3894(99)00152-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The amounts of equilibrium adsorption of phenol and 4-chlorophenol from water on non-ionic macroreticular resins were measured in the temperature range 288-318 K, It was shown that the isotherm data could not be fit by any conventional two- or three-parameter equation including the Langmuir, Freundlich, BET, and Redlich-Peterson equations over the entire range of concentration (1-32 mol m(-3)). They were well fit by combined BET equation or its modified form with the Freundlich or Langmuir equation, depending on the types of solutes and the resins. Such different fitting results could be related to the solute-resin interactions owing to the relatively wide pore size distribution of the resins. The effect of temperature on adsorption equilibrium was also discussed. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:171 / 183
页数:13
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