Infrared spectroscopic investigations on the metallation of terminal alkynes by Zn(OTf)2

被引：60

作者：

Fässler, R ^{[1
]}

Tomooka, CS ^{[1
]}

Frantz, DE ^{[1
]}

Carreira, EM ^{[1
]}

机构：

[1] ETH Honggerberg, Dept Chem, Organ Chem Lab, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2004年 / 101卷 / 16期

关键词：

D O I：

10.1073/pnas.0308326101

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

An IR study of terminal acetylenes and Zn(OTf)(2) in the presence of amine bases provides evidence that is consistent with the generation of Zn-acetylides.

引用

页码：5843 / 5845

页数：3

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