Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Graphene

被引:1139
作者
Shan, Changsheng [1 ,3 ]
Yang, Huafeng [1 ,3 ]
Song, Jiangfeng [1 ,3 ]
Han, Dongxue [1 ,2 ,3 ]
Ivaska, Ari [2 ]
Niu, Li [1 ,2 ,3 ]
机构
[1] Chinese Acad Sci, Grad Univ, Changchun 130022, Peoples R China
[2] Abo Akad Univ, Proc Chem Ctr, Analyt Chem Lab, FI-20500 Turku, Finland
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
关键词
DIRECT ELECTRON-TRANSFER; FUNCTIONALIZED IONIC LIQUID; CARBON NANOTUBES; GOLD NANOPARTICLES; GRAPHITE OXIDE; IMMOBILIZING ENZYME; AQUEOUS DISPERSIONS; SOL-GEL; SHEETS; FILMS;
D O I
10.1021/ac802193c
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We first reported that polyvinylpyrrolidone-protected graphene was dispersed well in water and had good electrochemical reduction toward O-2 and H2O2. With glucose oxidase (GOD) as an enzyme model, we constructed a novel polyvinylpyrrolidone-proteeted graphene/polyethylenimine-ftmctionalized ionic liquid/GOD electrochemical biosensor, which achieved the direct electron transfer of GOD, maintained its bioactivity and showed potential application for the fabrication of novel glucose biosensors with linear glucose response up to 14 mM.
引用
收藏
页码:2378 / 2382
页数:5
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