Synthesis of surface-modified nanoparticles via cycloaddition-reactions

被引:26
作者
Binder, Wolfgang H. [1 ]
Petraru, Laura [1 ]
Sachenshofer, Robert [1 ]
Zirbs, Ronald [1 ]
机构
[1] Vienna Univ Technol, Inst Appl Synthet Chem, Vienna, Austria
来源
MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 07期
关键词
nanochemistry; 1,3-dipolar cycloaddition-reactions; hydrogen bonds; atomic force microscopy;
D O I
10.1007/s00706-006-0483-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The surface modification of nanoparticles via azide/alkine-1,3-dipolar cycloaddition-reactions is described. Ligand exchange onto various nanoparticles was monitored by H-1 NMR spectroscopy and formed the basis for the attachment of ligands onto the nanoparticles and their subsequent modification by dipolar cycloaddition reactions. Nanoparticle-surfaces were monitored by binding onto self-assembled monolayers derivatized with matching supramolecular interactions after derivatization.
引用
收藏
页码:835 / 841
页数:7
相关论文
共 23 条
[1]   Photochemical instability of CdSe nanocrystals coated by hydrophilic thiols [J].
Aldana, J ;
Wang, YA ;
Peng, XG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8844-8850
[2]  
Binder W.H., 2004, POLYM PREPR, V45, P692
[3]   Tunable materials from hydrogen-bonded pseudo block copolymers [J].
Binder, WH ;
Bernstorff, S ;
Kluger, C ;
Petraru, L ;
Kunz, MJ .
ADVANCED MATERIALS, 2005, 17 (23) :2824-+
[4]   Directed nanoparticle binding onto microphase-separated block copolymer thin films [J].
Binder, WH ;
Kluger, C ;
Straif, CJ ;
Friedbacher, G .
MACROMOLECULES, 2005, 38 (23) :9405-9410
[5]   Supramolecular assembly of nauoparticles at liquid-liquid interfaces [J].
Binder, WH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (33) :5172-5175
[6]   Combining ring-opening metathesis polymerization (ROMP) with sharpless-type "click" reactions: An easy method for the preparation of side chain functionalized poly(oxynorbornenes) [J].
Binder, WH ;
Kluger, C .
MACROMOLECULES, 2004, 37 (25) :9321-9330
[7]   Synthesis and analysis of telechelic polyisobutylenes for hydrogen-bonded supramolecular pseudo-block copolymers [J].
Binder, WH ;
Kunz, MJ ;
Kluger, C ;
Hayn, G ;
Saf, R .
MACROMOLECULES, 2004, 37 (05) :1749-1759
[8]   Supramolecular poly(ether ketone)-polyisobutylene pseudo-block copolymers [J].
Binder, WH ;
Kunz, MJ ;
Ingolic, E .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (01) :162-172
[9]  
BINDER WH, 2006, IN PRESS CURR ORG CH
[10]  
BINDER WH, 2005, MONATSH CHEM, P19