Tilden Lecture: Shining light on metal catalysts

被引：17

作者：

Evans, J

机构：

[1] Department of Chemistry, University of Southampton

来源：

CHEMICAL SOCIETY REVIEWS | 1997年 / 26卷 / 01期

关键词：

D O I：

10.1039/cs9972600011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray absorption spectroscopy can provide local structural information about the reaction centres in metal catalysts. Developments in this technique are illustrated with the chemistry of oxide supported metals e.g. Rh(CO)(2)/titania and by studies on some homogeneous catalysts (rhodium-catalysed carbonylation and nickel catalysts for alkene catenation). Energy dispersive EXAFS promises the opportunity to probe the structures of short-lived reaction intermediates.

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页码：11 / 19

页数：9

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