XPS characterisation of plasma-treated and alumina-coated PMMA

被引:85
作者
Ben Amor, S
Baud, G
Jacquet, M
Nansé, G
Fioux, P
Nardin, M
机构
[1] CNRS, UPR 9069, Inst Chim Surfaces & Interfaces, F-68057 Mulhouse, France
[2] Univ Blaise Pascal, UPRES A 6002, Lab Mat Inorgan, F-63177 Clermont Ferrand, France
关键词
poly(methyl-methacrylate); alumina film; plasma treatment; XPS analysis;
D O I
10.1016/S0169-4332(99)00354-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present study is entirely devoted to an XPS analysis of (i) the surface of as received and plasma (argon, CO,) treated poly(methyl-methacrylate) (PMMA) and (ii) the interface between PMMA and alumina thin films, deposited by r.f. magnetron sputtering respectively on untreated and CO2 plasma-treated polymer films. As expected, important chemical modifications of PMMA surface are observed when this polymer is plasma-treated. Such modifications increase the level of interactions between alumina and the substrate. However, if the formation of aluminium carboxylate is observed at the interface, no covalent bonds between the alumina film and the polymer are evidenced. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:172 / 183
页数:12
相关论文
共 22 条
[1]  
BACHARI EM, 1999, IN PRESS THIN SOLID
[2]   Characterization of zirconia films deposited by rf magnetron sputtering [J].
Ben Amor, S ;
Rogier, B ;
Baud, G ;
Jacquet, M ;
Nardin, M .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1998, 57 (01) :28-39
[3]  
Ben Amor S, 1998, J ADHESION, V65, P307
[4]  
BENAMOR S, 1998, SURF COAT TECH, V63, P102
[5]  
BON M, 1991, APPL SURF SCI, V47, P149
[6]   ACID-BASE BEHAVIOR OF ALUMINUM AND SILICON-OXIDES - A COMBINATION OF 2 APPROACHES - XPS AND LEWIS ACIDO-BASICITY - REST POTENTIAL AND BRONSTED ACIDO-BASICITY [J].
CASAMASSIMA, M ;
DARQUECERETTI, E ;
ETCHEBERRY, A ;
AUCOUTURIER, M .
APPLIED SURFACE SCIENCE, 1991, 52 (03) :205-213
[7]   ESCA APPLIED TO POLYMERS .18. RF GLOW-DISCHARGE MODIFICATION OF POLYMERS IN HELIUM, NEON, ARGON, AND KRYPTON [J].
CLARK, DT ;
DILKS, A .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (05) :911-936
[8]   Characterization and adhesion study of thin alumina coatings sputtered on PFT [J].
Cueff, R ;
Baud, G ;
Benmalek, M ;
Besse, JP ;
Butruille, JR ;
Dunlop, HM ;
Jacquet, M .
THIN SOLID FILMS, 1995, 270 (1-2) :230-236
[9]   AN X-RAY PHOTOEMISSION SPECTROSCOPY STUDY OF CHEMICAL INTERACTIONS AT SILVER PLASMA MODIFIED POLYETHYLENE INTERFACES - CORRELATIONS WITH ADHESION [J].
GERENSER, LJ .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1988, 6 (05) :2897-2903
[10]   XPS STUDIES OF IN-SITU PLASMA-MODIFIED POLYMER SURFACES [J].
GERENSER, LJ .
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 1993, 7 (10) :1019-1040