Rapid assembly of oligosaccharides: 1,2-diacetal-mediated reactivity tuning in the coupling of glycosyl fluorides

被引：60

作者：

Baeschlin, DK ^{[1
]}

Green, LG ^{[1
]}

Hahn, MG ^{[1
]}

Hinzen, B ^{[1
]}

Ince, SJ ^{[1
]}

Ley, SV ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 01期

基金：

英国工程与自然科学研究理事会; 英国生物技术与生命科学研究理事会;

关键词：

D O I：

10.1016/S0957-4166(99)00519-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper describes the application of 1,2-diacetal protecting groups to control the reactivity tuning of glycosyl fluorides in oligosaccharide coupling reactions. The synthetic potential of this new methodology is demonstrated by the 'one-pot' synthesis of a linear pentasaccharide and the efficient assembly of the core oligosaccharide of the GPI anchor of yeast (Saccharomyces cerevisiae). (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：173 / 197

页数：25

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